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The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO 3 ) 2 (pyz) 3 has an intrachain coupling J = 13.7(1) K ( ) and exhibits a state of long-range magnetic order below T N = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be | J ′/ J | = 3.3 × 10 −3 , demonstrating a high degree of isolation for the Cu chains.more » « less
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Manson, Jamie L.; Manson, Zachary E.; Sargent, Ashley; Villa, Danielle Y.; Etten, Nicole L.; Blackmore, William J.A.; Curley, Samuel P.M.; Williams, Robert C.; Brambleby, Jamie; Goddard, Paul A.; et al (, Polyhedron)
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Manson, Jamie L.; Brambleby, Jamie; Goddard, Paul A.; Spurgeon, Peter M.; Villa, Jacqueline A.; Liu, Junjie; Ghannadzadeh, Saman; Foronda, Francesca; Singleton, John; Lancaster, Tom; et al (, Scientific Reports)
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